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Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures

Received: 9 July 2022     Accepted: 8 August 2022     Published: 17 August 2022
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Abstract

In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.

Published in American Journal of Physical Chemistry (Volume 11, Issue 3)
DOI 10.11648/j.ajpc.20221103.11
Page(s) 45-51
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2022. Published by Science Publishing Group

Keywords

Molecular Interaction, Density, Excess Viscosity

References
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    Victoria Bennett, Nimibofa Ayawei. (2022). Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. American Journal of Physical Chemistry, 11(3), 45-51. https://doi.org/10.11648/j.ajpc.20221103.11

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    Victoria Bennett; Nimibofa Ayawei. Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. Am. J. Phys. Chem. 2022, 11(3), 45-51. doi: 10.11648/j.ajpc.20221103.11

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    AMA Style

    Victoria Bennett, Nimibofa Ayawei. Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. Am J Phys Chem. 2022;11(3):45-51. doi: 10.11648/j.ajpc.20221103.11

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  • @article{10.11648/j.ajpc.20221103.11,
      author = {Victoria Bennett and Nimibofa Ayawei},
      title = {Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures},
      journal = {American Journal of Physical Chemistry},
      volume = {11},
      number = {3},
      pages = {45-51},
      doi = {10.11648/j.ajpc.20221103.11},
      url = {https://doi.org/10.11648/j.ajpc.20221103.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20221103.11},
      abstract = {In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures
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    AU  - Nimibofa Ayawei
    Y1  - 2022/08/17
    PY  - 2022
    N1  - https://doi.org/10.11648/j.ajpc.20221103.11
    DO  - 10.11648/j.ajpc.20221103.11
    T2  - American Journal of Physical Chemistry
    JF  - American Journal of Physical Chemistry
    JO  - American Journal of Physical Chemistry
    SP  - 45
    EP  - 51
    PB  - Science Publishing Group
    SN  - 2327-2449
    UR  - https://doi.org/10.11648/j.ajpc.20221103.11
    AB  - In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.
    VL  - 11
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Author Information
  • Department of Chemical Sciences, Faculty of Basic and Applied Sciences, University of Africa, Toru-Orua, Sagbama, Nigeria

  • Department of Chemistry, Faculty of Science, Medical University, Yenagoa, Nigeria

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